Search results for " Conjugation"
showing 10 items of 48 documents
Interpretation of negative birefringence observed in strong-field optical pump-probe experiments: High-order Kerr and plasma grating effects
2013
The analysis of negative birefringence optically induced in major air components (Loriot et al., [1, 2]) is revisited in light of the recently reported plasma grating-induced phase-shift effect predicted for strong field pump-probe experiments (Wahlstrand and Milchberg, [3]). The nonlinear birefrin- gence induced by a short and intense laser pulse in argon is measured by femtosecond time-resolved polarimetry. The experiments are performed with degenerate colors, where the pump and probe beam share the same spectrum, or with two different colors and non-overlapping spectra. The in- terpretation of the experimental results is substantiated using a numerical 3D+1 model accounting for nonlinear…
Probing the Folding of Peptide–Polymer Conjugates Using the π-Dimerization of Viologen End-Groups
2020
The synthesis of a foldable viologen-functionalized peptide–polymer conjugate is presented. The ABA-type triblock conjugate with a PEG polymer was capped with a FHFHF pentapeptide sequence and further modified with a viologen building block at both chain ends. The pH-responsive peptide domains fold into an intermediate structure inducing close proximity of the viologen units, which upon a reduction step form π-dimers of the radical cation. Overall the intramolecular folding and intermolecular self-assembly process leads to the formation of supramolecular nanorods. Mixing of viologen-peptide–polymer conjugates with unfunctionalized conjugates leads to crosslinking of the nanorods and hydroge…
Oscillation spectra of semilinear photorefractive coherent oscillator with two pump waves
2002
The transition of the single-frequency oscillation of a semilinear photorefractive coherent oscillator for sufficiently large coupling strengths into two-frequency oscillation is predicted and is observed experimentally. The critical value of coupling strength at which the bifurcation occurs is a function of pump-intensity ratio and cavity losses. For certain combinations of these parameters, the critical coupling strength for spectrum bifurcation becomes smaller than the threshold coupling strength: in these cases double-frequency oscillation appears at the threshold. The supercritical bifurcation in the oscillation spectrum is analogous to the second-order phase transition.
Conjugative ESBL plasmids differ in their potential to rescue susceptible bacteria via horizontal gene transfer in lethal antibiotic concentrations.
2017
Conjugative ESBL plasmids differ in their potential to rescue susceptible bacteria via horizontal gene transfer in lethal antibiotic concentrations
Transverse nonlinear optics in heavy-metal-oxide glass
2008
6 pags. ; 9 figs.
Phase conjugation in BaTiO 3 by use of the indirect photorefractive coupling of orthogonally polarized light waves
1998
A phase-conjugate wave is generated when an ordinary (extraordinary) signal wave is mixed with two counterpropagating extraordinary (ordinary) waves in the plane normal to the BaTiO3 polar axis. The photorefractive grating that couples the ordinary and the extraordinary waves appears if the incident waves induce a noticeable conical parametric scattering; this grating is a difference grating of many noisy scattering gratings recorded by means of the usual diffusion-mediated charge transport. For comparable intensities of signal and pump waves this type of nonlinear wave mixing is much more efficient than that which is due to the circular bulk photovoltaic effect.
Conformational investigation of alpha,beta-dehydropeptides. VIII. N-acetyl-alpha,beta-dehydroamino acid N'-methylamides: conformation and electron de…
2009
The Fourier transform infrared spectra are analyzed in the regions of Vs(N-H), amide I, amide II and Vs(C alpha = C beta) bands for a series of Ac-delta Xaa-NHMe, where delta Xaa = delta Ala, (Z)-delta Abu, (Z)-delta Leu, (Z)-delta Phe and delta Val, to determine the predominant solution conformation of these alpha,beta-dehydropeptide-related molecules and the electron distribution perturbation in their amide bonds. The measurements were performed in dichloromethane (DCM). To confirm and rationalize the assignments, the spectra of the respective series of saturated Ac-Xaa-NHMe, recorded in DCM, and the spectra of these two series of unsaturated and saturated compounds, recorded in acetonitr…
Backward frequency doubling of near infrared picosecond pulses.
2014
We report on backward second-harmonic generation using ps laser pulses in congruent lithium niobate with 3.2 µm periodic poling. Three resonant peaks were measured between 1530 and 1730 nm, corresponding to 16th, 17th and 18th quasi-phase-matching orders in the backward configuration, with a conversion efficiency of 4.75 x 10(-5%)/W for the 16th order. We could also discriminate the contributions from inverted domains randomized in duty-cycle.
<title>Phase conjugation properties of a-As-S-Se films</title>
2006
Light wavefront inversion (phase conjugation) in a-As-S-Se films has been studied experimentally. Phase conjugation (PC) of plane and spherical waves is carried out in a-As40S15Se45 films using degenerate four-wave-mixing (DFWM) geometry at 633 nm. In the plane wave case simultaneous PC efficiency and DE measurements have been made versus exposure time, light intensity and holographic grating period. The maximal PC efficiency was 2.3% and the minimal PC specific recording energy was 2 J/(cm2%) whereas the maximal DE was 0.9% and the minimal specific hologram recording energy was 10 J/(cm2%). The optimal grating period was 2 μm. When compared to a-Se films a-As-S-Se films exhibit lower PC ef…
Second-order optical phase transition in a semilinear photorefractive oscillator with two counterpropagating pump waves
2002
Soft-mode onset of coherent oscillation is revealed in a semilinear cavity with two counterpropagating pump waves. From the dynamics of the oscillation intensity and the dynamics of the grating decay with the feedback applied, critical behavior is detected: Both the characteristic time of oscillation onset and grating decay time go to infinity exactly at the threshold coupling strength. A conclusion is made about the similarity of this type of oscillator to the second-order phase transition.